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Engineering Physics

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M&#246;ssbauer Spectroscopy of Impurity Zinc Atoms in Alkali Metal Halides and Silver
Doronin V.A., Bobokhuzhaev K.U., Kiselev V.S., Marchenko A.V., Seregin P.P.

Shifts and parameters of the nuclear quadrupole interaction of the Mössbauer spectra of 67Cu(67Zn)
impurity atoms in the crystal lattices of sodium, potassium and silver halides. A change in the
electronic structure of impurity zinc atoms is demonstrated depending on the chemical nature of the
atoms of the immediate environment and their coordination. It is shown that the vacancy formed
as a result of the substitution of alkali metal and silver ions by zinc centers is located in the fi rst
coordination sphere from the impurity atom.
Keywords: alkali metal and silver halide crystals, impurity zinc atoms, Mössbauer spectroscopy.


DOI: 10.25791/infi zik.1.2024.1378

Pp. 14-19.

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